Efflorescent sulfate minerals of the Karabash mining/Smelting area, Ural mountains, Russia
J. Hechler, V. Udachin, P. Aminov, P.J. Beckett, G.A. Spiers
UDК 553.252.2, 549.76
Karabash is a copper smelting town in the Chelyabinsk district of the Southern Ural mountains of Russia. The town is in close proximity to a large copper deposit and resultant mining activities. Eforescent minerals from tailings outwash were collected from the mining-impacted landscape. The eforescent sulfates collected from a variety of sites on tailings outwash adjacent the streams downstream from the Karabash mining zone were dominated by hydrated Fe-Mg-Al sulfates (halotrichite-pickeringite series, melanterite, pentahydrite, magnesiocopiapite, and coquimbite). The eforescents noted in the tailings outwash site in Karabash appear to be water-soluble salts that crystallized during evaporation of waste-water runof from the tailings area. The oxidation of the mine wastes acts to liberate sulfur, creating an acidic drainage that leaches both the mine tailings (mobilizing iron and other potentially harmful metals) as well as elements from the rocks around the tailings site. Acid mine drainage, mine and smelter fallout pose a signifcant environmental concern to the Karabash region.
Figures 5. References 13.
Key words: eforescent sulfates, tailings, weathering, XRD, SEM.
J. Hechler, Ontario Ministry of Energy, Northern Development and Mines, Cedar st. 159, Sudbury, ON P3E 6A5 Canada;Laurentian University, Ramsey Lake Rd., Sudbury, ON P3E 2C6 Canada;
V. Udachin, Institute of Mineralogy UB RAS, Miass, Chelyabinsk district, 456317 Russia; udachin@mineralogy ru
P. Aminov, Institute of Mineralogy UB RAS, Miass, Chelyabinsk district, 456317 Russia;
P.J. Beckett, Laurentian University, Ramsey Lake Rd., Sudbury, ON P3E 2C6 Canada;
G.A. Spiers, Laurentian University, Ramsey Lake Rd., Sudbury, ON P3E 2C6 Canada;
- Adamo P., Dudka S., Wilson M.J., McHardy W.J. (1996) Chemical and mineralogical forms of Cu and Ni in contaminated soils from the Sudbury mining and smelting region, Canada. Environmental Pollution, 91(1), 11-19.
- Belogub E.V., Shcherbakova E.P. Nikandrova N.K. (2007) [Sulfates of the Urals: prevalence, crystal, genesis]. Moscow, Nauka, 160 p. (in Russian).
- Blowes D.W., Ptacek C.J., Jambor J.L., Weisener C.G. (2003) The geochemistry of acid mine drainage. Treatise on Geochemistry, 9, 149-204.
- Blowes D.W., Ptacek C.J., Jambor J.L., Weisener C.G., Paktunc D., Gould W.D., Johnson D.B. (2014) The geochemistry of acid mine drainage. In: Turekian KK, Holland HD (eds) Treatise of Geochemistry (2nd Edition). Amsterdam, Elsevier. 11, 131-190.
- Brooks S.J., Udachin V., Williamson B.J. (2005) Impact of copper smelting on lakes in the Southern Ural Mountains, Russia, inferred from chironomids. Journal of Paleolimnology, 33, 229-241.
- Carro B., Borrego J., López-González N., Grande J.A., Gómez T., de la Torre M.L., Valente T. (2011) Impact of acid mine drainage on the hydrogeochemical characteristics of the Tinto-Odiel Estuary (SW Spain). Journal of Iberian Geology, 37, 87-96.
- Evangelou V.P., Zhang Y.L. (1995) A review: pyrite oxidation mechanisms and acid mine drainage prevention. Critical Reviews in Environmental Science and Technology, 25, 141-199.
- Jerz J.K., Rimstidt J.D. (2003) Eforescent iron sulfate minerals: Paragenesis, relative stability, and environmental impact. American Mineralogist, 88, 1919-1932.
- Keith C.N., Vaughan D.J. ( 2000) Mechanisms and rates of sulfde oxidation in relation to the problems of acid rock (mine) drainage. In: Campbell L.S., Valsami-Jones E., Batchelder M. (Eds.). Environmental Mineralogy: Microbial interactions, anthropogenic infuences, contaminated land and waste. The Mineralogical Society Series, 9, 117-139.
- Nordstrom D.K., Alpers C.N. (1999) Negative pH, eforescent mineralogy, and consequences for environmental restoration at the Iron Mountain Superfund site, California. Proceedings of the National Academy of Science U.S.A., 96, 3455-3462.
- Nordstrom D.K., Southam G. (1997) Geomicrobiology of sulfde mineral oxidation. In: Benfeld J.F., Nealson K.H. (Eds.). Geomicrobiology: Interactions between microbes and minerals. Reviews in Mineralogy. Mineralogical Society of America, 35, 361-390.
- Williamson B.J., Udachin V.N., Purvis O.W., Spiro B., Cressey G., Jones G.C. (2004) Characterisation of airborne particulate pollution in the Cu smelter and former mining town of Karabash, South Ural Mountains of Russia. Environmental Monitoring and Assessment, 98, 235-259.
- Udachin V., Williamson B.J., Purvis O.W, Spiro B., Dubbin W., Brooks S., Coste B., Herrington R.J., Mikhailova I. (2003) Assessment of environmental impacts of active smelter operations and abandoned mines in Karabash, Ural Mountains of Russia. Sustainable Development, (11), 1-10.
МINERALOGY № 4 2018