Gold-base metal mineralization of the Mikheevsky (Novonikolaevsky) porphyry copper ore cluster, South Urals
O.Yu. Plotinskaya, V.V. Khrebtievsky, E.V. Kovalchuk, M.M. Savostyanova
The paper describes different types of base metal mineralization of the Mikheevsky (Novonikolaevsky) ore cluster (South Urals, Russia). At the Mikheevskoe porphyry copper deposit, gold-base metal mineralization occurs as subepithermal veins up to 30 cm thick with pyrite, arsenopyrite, fahlore (tennantite-tetrahedrite-(Fe) and argentotetrahedrite-(Fe)), sphalerite and galena. Minor minerals include native gold of varying composition and polybasite. At the Novonikolaevskoe skarn porphyry Cu deposit, early galena and sphalerite occur in massive sulfide ores of the post-skarn stage, while propylites hosts late galena and sphalerite, as well as fahlores (tennantite-(Fe, Zn)–tetrahedrite-(Zn)). Minor native gold and rare Те, Hg, Bi, Ni, W, In, and Sn minerals belong to the same assemblage. At the Zapadnoe porphyry Cu deposit, the base metal assemblage includes pyrite, fahlore (tennantite-tetrahedrite-(Zn)), galena, and sphalerite and is accompanied by quartz-sericite-carbonate alteration. These types of base metal mineralization formed at a similar temperature range (from 290–320 to 280–220 °С), but differ in chemical composition of major ore minerals and a set of rare ore minerals. This diversity is caused by zoning and different evolution stages of a telescoped porphyry system.
Keywords: South Urals, Mikheevskoe porphyry deposit, Zapadnoe porphyry deposit, Novonikolaevskoe skarn porphyry deposit, copper, fahlore, sphalerite, galena, native gold.
Funding. This work was supported by state contract of the Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry RAS (Moscow, Russia).
Acknowledgements. The authors express their gratitude to the management of the Mikheevsky GOK (Chelyabinsk region, Russia) for support during fieldwork, staff of the Laboratory of Local Analytical Methods of the Moscow State University (Moscow, Russia) and Laboratory of Crystal Mineral Chemistry of the Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry RAS (Moscow, Russia) for electron microprobe analysis, and Ya.E. Soldatova for assistance with data processing.
Conflict of interest. The authors declare that they have no conflicts of interest.
Author contribution. Plotinskaya O.Yu. – concept development, research, visualization, writing, editing the final version of the manuscript: Khrebtievsky V.V. – concept development, research, visualization, writing: Kovalchuk E.V. – research, Savostianova M.M. – research.
For citation: Plotinskaya O.Yu., Khrebtievsky V.V., Kovalchuk E.V., Savostyanova M.M. Gold-base metal mineralization of the Mikheevsky (Novonikolaevsky) porphyry copper ore cluster, South Urals. Mineralogy, 2026, 12(3), 66–92. https://doi.org/10.35597/2313-545X-2026-12-3-4
Received 29.05.2026, revised 30.76.2026, accepted 06.08.2026
Olga Yu. Plotinskaya – Doct. Sci. (Geol.-Mineral), Leading Researcher, Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry RAS, Moscow, Russia; plotin@igem.ru
Vladimir V. Khrebtievsky – Post-Graduate Student, Moscow State University, Moscow, Russia; st064292@gmail.com
Elena V. Kovalchuk – Cand. Sci. (Geol.-Mineral), Scientific Researcher, Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry RAS, Moscow, Russia; elena7kovalchuk@gmail.com
Margarite M. Savostyanova – Senior Specialist, Fedorovsky All-Russian Scientific Research Institute of Mineral Resources, Moscow, Russia; savostyanova_m@inbox.ru
- Azovskova O.B., Rovnushkin M.Y., Bairamgali-na L.N., Gemel V.A. (2022) Uranium and thorium mineralization in ores of the Mikheevskoe porphyry copper deposit, South Urals. Metallogeniya drevnikh i sovremennykh okeanov-2022. Ot veshchestvennogo sostava k modelyam i prognozirovaniyu mestorozhdeniy (Metallogeny of Ancient and Modern Oceans-2022. From Composition to Models and Forecasting Deposits). Miass, YuU FNTs MiG UrO RAN, 114–117. (in Russian)
- Azovskova O.B., Rovnushkin M.Y., Moshev S.I., Bairamgalina L.N. (2018) Bismuth and uranium mineralization at the deep horizons of the Gumeshevskoe deposit, Central Urals. XII Mezhregionalnaya konferentsiya “Geologiya, poleznye iskopaemye i problemy geoekologii Bashkortostana, Urala i sopredelnyh territoriy” (XII Interregional Conference “Geology, Mineral Deposits, and Problems of Geoecology of Bashkortostan, Urals, and Adjacent Territories”). Ufa, IG UFITs RAN, 218–220. (in Russian)
- Bailey S.W. (1988) Chlorites: structures and crystal chemistry / Hydrous Phyllosilicates (Exclusive of Micas). Reviews in Mineralogy, 19, 347–403.
- Bauer M.E., Seifert T., Burisch M., Krause J., Richter N., Gutzmer J. (2019) Indium-bearing sulfides from the Hämmerlein skarn deposit, Erzgebirge, Germany: evidence for late-stage diffusion of indium into sphalerite. Mineralium Deposita, 54, 175–192. https://doi.org/10.1007/s00126-017-0773-1
- Bazarkina E.F., Zotov A.V., Akinfiev N.N. (2010) Pressure-dependent stability of cadmium chloride complexes: Potentiometric measurements at 1–1000 bar and 25 °C. Geology of Ore Deposits, 52, 167–178. https://doi.org/10.1134/S1075701510020054
- Belgorodsky E.A., Cherkashov S.A., Grabezhev A.I., Shargorodsky B.M. (1991) Porphyry copper Novonikolayevsky ore cluster. Sverdlovsk, UrO AN SSSR, 54 p. (in Russian)
- Bukhanova D.S. (2021) Mineralogical and geochemical features of the Malmyzh gold-copper porphyry deposit, Khabarovsk krai. (Candidate dissertation). Vladivostok, DVGI DVO RAN, 200 p. (in Russian)
- Burmistrov A.A., Khrebtievsky V.V., Erastov E.A. (2023) Preliminary studies of petrophysical properties and types and intensity of metasomatic alteration of rocks and ores of the Novonikolaevskoe area of the Mikheevskoe porphyry copper deposit (South Urals). Nedropolzovanie XXI vek (Subsoil Use XXI Century), 3–4(100), 42–51. (in Russian)
- Catchpole H., Kouzmanov K., Fontboté L. (2012) Copper-excess stannoidite and tennantite-tetrahedrite as proxies for hydrothermal fluid evolution in a zoned cordilleran base metal district, Morococha, Central Peru. The Canadian Mineralogist, 50, 719–743. https://doi.org/10.3749/canmin.50.3.719
- Chen S. C., Yu J. J., Bi M. F., Lehmann B. (2022) Tin-bearing minerals at the Furong tin deposit, South China: Implications for tin mineralization. Chemie der Erde, 82(1), 125856. https://doi.org/10.1016/j.chemer.2021.125856
- Cook N.J., Ciobanu C.L., Pring A., Skinner W., Shimizu M., Danyushevsky L., Saini-Eidukat B., Melcher F. (2009) Trace and minor elements in sphalerite: a LA-ICP-MS study. Geochimica et Cosmochimica Acta, 73, 4761–4791. https://doi.org/10.1016/j.gca.2009.05.045.
- Czamanske G.K. (1974) The FeS content of sphalerite along the chalcopyrite-pyrite-bornite sulfur fugacity buffer. Economic Geology, 69, 1328–1334. https://doi.org/10.2113/gsecongeo.69.8.1328
- Donahue K.M. (2002) Geochemistry, geology and geochronology of the Victorio mining district, Luna County, New Mexico: Linking skarn and porphyry systems to carbonate-hosted lead-zinc replacement deposits. MSc Thesis. Socorro, New Mexico, New Mexico Institute of Mining and Technology, 186 p.
- Einaudi M.T., Meinert L.D., Newberry R.J. (1981) Skarn deposits. Economic Geology, 75, 317–391. https://doi.org/10.5382/AV75.11.
- Girfanov M.M., Sergeeva N.E., Shishakov V.B.(1991) Ore-metasomatic zonation of the Mikheevskoe porphyry copper deposit in the South Urals. Vestnik Moskovskogo universiteta (Moscow State University Bulletin), 5, 75–79. (in Russian)
- Gorbunov A.A., Alikin O.V., Zakharova A.A., Guseva T.A., Rudashevsky V.N., Gemel V.A. (2019) Mineralogical features of ores of the Mikheevskoe deposit, Novonikolaevsky and Zapadny areas (South Urals). Uralskaya mineralogicheskaya shkola-2019 (Urals Mineralogical School-2019). Yekaterinburg, UGGU, 41–44. (in Russian)
- Grabezhev A.I. (2014) Novonikolaevsky (Mo, Au)-Cu porphyry ore cluster (South Urals): petrogeochemistry of ore-bearing granitoids and metasomatites. Litosphera (Lithosphere Russia), 2, 60−76. (in Russian)
- Grabezhev A.I., Belgorodsky E.A. (1992) Productive granitoids and metasomatites of porphyry copper deposits: example of the Urals. Yekaterinburg, UrO RAN, 199 p. (in Russian)
- Grabezhev A.I., Ronkin Y.L. (2011) U-Pb age of zircons from ore-bearing granitoids of porphyry copper deposits in the South Urals. Litosphera (Lithosphere Russia), 3, 104–116. (in Russian)
- Hedenquist J.W., Arribas A.R., Gonzalez-Urien E. (2000) Exploration for epithermal gold deposits. Reviews in Economic Geology, 13, 245−277. https://doi.org/10.5382/Rev.13.07
https://nedradv.ru/nedradv/ru/places?mineral=ea137769ab1dc8b338a79c54c3009281 (last access on June 28, 2026) - Kesler S.E., Chryssoulis S.L., Simon G. (2002) Gold in porphyry copper deposits: Its distribution and fate. Ore Geology Reviews, 21, 103–124. https://doi.org/10.1016/S0169-1368(02)00084-7
- Khrebtievsky V.V. (2024) Mineral formation sequence and new Sn and Te minerals at the Novonikolaevskoe deposit (South Urals). Metallogeniya drevnikh i sovremennykh okeanov-2024. Rudogenez (Metallogeny of Ancient and Modern Oceans-2024. Ore Genesis). Miass, SU FNTs MiG UrO RAN, 144–147. (in Russian)
- Khrebtievsky V.V. (2025) Features of the distribution of Cu and Au contents at the Novonikolaevskoe porphyry copper deposit (South Urals). Metallogeniya drevnikh i sovremennykh okeanov-2025. Ot gipotez rudogeneza k kriteriyam prognozirovaniya (Metallogeny of Ancient and Modern Oceans-2025. From Ore Genesis Hypotheses to Forecasting Criteria). Miass, SU FNTs MiG UrO RAN, 104–107. (in Russian)
- Khrebtievsky V.V. (2026) Hydrothermal zonation and genesis of the Novonikolaevskoe skarn copper porphyry deposit (Southern Urals). Metallogeniya drevnikh i sovremennykh okeanov-2026. Strategicheskie elementy: mineralogo-geokhimicheskie i tsifrovye modeli (Metallogeny of Ancient and Modern Oceans-2026. Strategic Elements: Mineralogical and Geochemical and Digital Models). Miass, SU FNTs MiG UrO RAN, 125–128. (in Russian)
- Khrebtievsky V.V., Plotinskaya O.Y. (2026) Skarn garnets of the Novonikolaevskoe copper deposit (South Urals). Mineralogiya (Mineralogy), 12(1), 44–59. https://doi.org/10.35597/2313-545X-2026-12-1-3 (in Russian)
- Kiseleva G.D., Kovalenker V.A., Borisovsky S.E., Yazykova Yu.I., Trubkin N.V. (2026) U-Th-REE mineralization of the Bystrinsk skarn-porphyry Au–Cu–Fe deposit (Eastern Transbaikalia): typomorphic characteristics, peculiarities of formation, and genetic implications. Geology of Ore Deposits, 68, 396–412. https://doi.org/10.1134/S1075701525600926
- Kotelnikov A.R., Suk N.I., Kotelnikova Z.A., Shchekina T.I., Kalinin G.M. (2012) Mineral geothermometers for low-temperature parageneses. Vestnik ONZ RAN (Bulletin of the Earth Sciences Department of the Russian Academy of Sciences), 4. https://doi.org/10.2205/2012NZ_ASEMPG (in Russian)
- Kovalenker V.A. (2006) Formation conditions and causes of large-scale concentration of gold, porphyry, and epithermal deposits. In: Krupnye i superkrupnye mestorozdeniya rudnyh poleznyh iskopaemyh (Large and Super-Large Deposits of Ore Mineral Deposits), vol. 2. Moscow, IGEM RAN, 143–214. (in Russian)
- Kovalenker V.A., Kiseleva G.D., Krylova T.L., Andreeva O.V. (2011) Mineralogy and ore formation conditions of the Bugdaya Au-bearing W-Mo porphyry deposit, Eastern Transbaikal Region, Russia. Geology of Ore Deposits, 53, 93–125. https://doi.org/10.1134/S1075701511020048
- Kretschmar U., Scott S.D. (1976) Phase relations involving arsenopyrite in the system Fe-As-S and their application. The Canadian Mineralogist, 14(3), 364–386.
- Kuzhuget R.V., Ankusheva N.N., Losev V.I. Kalinin Yu. A., Shavekina A.Sh., Bayir-Ool A.V., Vikentyev I.V. (2026) Kyzyk-Chadr Au–Mo–Cu porphyry deposit (Eastern Tuva, Russia): noble-metal mineralization, PT-parameters and ore-bearing fluid composition. Geology of Ore Deposits, 68, 413–441. https://doi.org/10.1134/S1075701525600744
- Kuznetsov A.Z., Velikanov A.Y., Arafailov A.E., Izmailov M.R., Morozova G.V., Budnik T.L., Ental’tsev E.V., Panfilenkova O.V., Tarasova N.N. (2020) Unpublished report with operative calculation of copper porphyry ore reserves of the Novonikolaevsky area (Zapadnoe and Novonikolaevskoe ore occurrences) of the Mikheevskoe deposit as of 01.01.2020 in the Kartaly and Varna districts of the Chelyabinsk region. Yekaterinburg, OOO Geosintez, 475 p. (in Russian)
- Kwak T.A.P. (1987) W-Sn skarn deposits and related metamorphic skarns and granitoids. Amsterdam-Oxford-New York, Elsevier, 451 p.
- Lipson R. (2014) The promise and perils of porphyry deposits in the future of gold production. SEG Newsletter, 98, 1–21. https://doi.org/10.5382/SEGnews.2014-98.fea
- Marushchenko L.I., Baksheev I.A., Nagornaya E.V., Chitalin A.F., Nikolaev Y.N., Vlasov E.A. (2018) Compositional evolution of the tetrahedrite solid solution in porphyry-epithermal system: A case study of the Baimka Cu-Mo-Au trend, Chukchi Peninsula, Russia. Ore Geology Reviews, 103, 21–37. https://doi.org/10.1016/j.oregeorev.2017.01.018
- Meinert L.D. (1992) Skarns and skarn deposits. Geoscience Canada, 19, 145–162.
- Meinert L.D., Dipple G.M., Nicolescu S. (2005) World skarn deposits. Economic Geology, 100, 299–336. https://doi.org/10.5382/AV100.11
- Monnier L., Salvi S., Melleton J., Bailly L., Béziat D., de Parseval P., Gouy S., Lach P. (2019) Multiple generations of wolframite mineralization in the Echassieres district (Massif Central, France). Minerals, 9(10), 637. https://doi.org/10.3390/min9100637
- Nikolaev Y.N., Baksheev I.A., Prokofiev V.Y., Nagornaya E.V., Marushchenko L.I., Sidorina Yu.N., Chitalin A.F., Kal’ko I.A. (2016) Gold–silver mineralization in porphyry–epithermal systems of the Baimka trend, western Chukchi Peninsula, Russia. Geology of Ore Deposits, 58, 284–307. https://doi.org/10.1134/S107570151604005X
- Plotinskaya O.Yu., Kovalchuk E.V. (2023) Fahlores from porphyry Cu-(Mo) deposits of the Urals. Mineralogiya (Mineralogy), 8(3), 5–22. https://doi.org/10.35597/2313-545X-2022-8-3-1 (in Russian)
- Plotinskaya O. Y., Kovalchuk E.V. (2025) Co and Ni minerals in ores of the Mikheevskoe porphyry copper deposit (South Urals). Mineralogiya (Mineralogy), 11(1), 17–27. https://doi.org/10.35597/2313-545X-2025-11-1-2 (in Russian)
- Plotinskaya O.Y., Azovskova O.B., Abramov S.S., Groznova E.O., Novoselov K.A., Seltmann R., Spratt J. (2018) Precious metals assemblages at the Mikheevskoe porphyry copper deposit (South Urals, Russia) as proxies of epithermal overprinting. Ore Geology Reviews, 94, 239–260. https://doi.org/10.1016/j.oregeorev.2018.01.025
- Plotinskaya O.Yu., Grabezhev A.I., Seltmann R. (2015) Rhenium in ores of the Mikheevskoe Mo-Cu porphyry deposit, South Urals. Geology of Ore Deposits, 57(2), 118–132. https://doi.org/10.1134/S1075701515020051
- Plotinskaya O.Y., Grabezhev A.I., Tessalina S., Seltmann R., Groznova E.O., Abramov S.S. (2017) Porphyry deposits of the Urals: geological framework and metallogeny. Ore Geology Reviews, 85, 153–173. https://doi.org/10.1016/j.oregeorev.2016.07.002
- Plotinskaya O.Y., Azovskova O.B., Belogub E. V. (2025) Telluride Mineralogy in Ores of the Birgilda Porphyry Copper Deposit (South Urals, Russia). Geology of Ore Deposits, 67(6), 799‒811. https://doi.org/10.1134/S1075701525600306
- Pribavkin S.V., Soroka E.I., Azovskova O.B., Smoleva I.V., Leonova L.V., Gottman I.A., Sustavov S.G., Rovnushkin M.Yu. (2023) Association of siderite with iron sulfides and silicates in rocks of the Mikheevskoe Cu(Mo,Au) porphyry deposit (Southern Urals). Geology of Ore Deposits, 65, 332–345. https://doi.org/ 10.1134/s1075701523040049
- Puchkov V.N. (2017) General features relating to the occurrence of mineral deposits in the Urals: What, where, when and why. Ore Geology Reviews, 85, 4–29. https://doi.org/10.1016/j.oregeorev.2016.01.005
- Rovnushkin M.Y., Azovskova O.B. (2022) Rhenium-bearing molybdenite in the argillization zone of the Mikheevskoe molybdenum-copper-porphyry deposit (Southern Urals) Izvestiya Ural’skogo gosudarstvennogo gornogo universiteta (News of the Urals State Mining University), 3(67), 7–13. http://doi.org/10.21440/2307-2091-2022-3-7-13
- Scott C.D., Barnes H.L. (1971) Sphalerite geothermometry and geobarometry. Economic Geology, 66, 653–669. https://doi.org/10.2113/gsecongeo.66.4.653
- Shadchin M.V., Shvedov G.I., Makarov V.A., Lobastov B.M., Silyanov S.A., Serdyuk S.S. (2024) New data on mineralogy of ores of the Ak-Sug Au-Mo-Cu porphyry deposit (Northeastern Tuva). Mineralogiya (Mineralogy), 10(3), 32–51. https://doi.org/10.35597/2313-545X-2024-10-3-3 (in Russian)
- Shargorodsky B.M., Novikov I.M., Aksenov S.A. (2005) The Mikheevskoe porphyry copper ore deposit in the South Urals. Otechestvennaya geologiya (National Geology), 2, 57–61. (in Russian)
- Sillitoe R.H. (2010) Porphyry copper systems. Economic Geology, 105, 3–41. https://doi.org/10.2113/gsecongeo.105.1.3
- Singer D.A., Berger V.I., Moring B.C. (2008) Porphyry copper deposits of the world: database and grade and tonnage models. Reston, Virginia, US Geological Survey Open File Report 2008, 45 p.
- Tessalina S.G., Plotinskaya O.Y. (2017) Silurian to Carboniferous Re-Os molybdenite ages of the Kalinovskoe, Mikheevskoe and Talitsa Cu-Mo porphyry deposits in the Urals: implications for geodynamic setting. Ore Geology Reviews, 85, 174–180. http://doi.org/10.1016/j.oregeorev.2016.09.005
- Tevelev A.V, Kosheleva I.A, Burshtein E.F, et al. (2018) State Geological Map of the Russian Federation. Scale 1:200 000. Second Edition. South Ural Series. Sheet N-41-XXV (Kartaly). Explanatory Note. Moscow, Moskovsky filian FGBU VSEGEI, 175 p. (in Russian)
- Tian M., Xiao Y., Shang Y., Wang M., Li L., Zhao M., Kang D. (2026) The occurrence of Sn in the Shizhuyuan W-Sn polymetallic skarn-greisen deposit: Insights into the magmatic-hydrothermal Sn mineralization process. Ore Geology Reviews, 188, 1–15. https://doi.org/10.1016/j.oregeorev.2025.107026
- Zhao H., Shao Y., Zhang Y., Cao G., Zhao L., Zheng X. (2023) Big data mining on trace element geochemistry of sphalerite. Journal of Geochemical Exploration, 252. https://doi.org/10.1016/j.gexplo.2023.107254
- Zharikov V.A., Rusinov V.L., Marakushev A.A., Zaraysky G.P., Omelyanenko B.I., Pertsev N.N., Rass I.T., Andreeva O.V., Abramov S.S., Podlessky K.V. (1998) Metasomatism and metasomatic rocks. Moscow, Nauchniy mir, 492 p. (in Russian)
MINERALOGY 3 2026
