Mineralogy of bloomery slags of the Shuvakish ironworks plant (outskirts of Yekaterinburg, Sverdlovsk oblast)
Yu.V. Erokhin, A.V. Zakharov, L.V. Leonova
UDK 549.0+669.181.28(470.5) | https://doi.org/10.35597/2313-545X-2021-7-1-5 | Read PDF (RUS) |
The mineralogy of slags of the Shuvakish ironworks plant is studied. The plant had been operated during the reign of Peter the Great from 1704 to 1716 years and was located within the present-day northwestern outskirts of Yekaterinburg. The slags are composed of fayalite aggregate with a signifcant content of hercynite and wustite and contain spherules of iron, glass, leucite and ferromerrillite. The chemical composition of rock-forming and ore minerals is determined on a JSM-6390LV (Jeol) SEM equipped with an INCA Energy 450 X-Max 80 EDS (Oxford Instruments) (Institute of Geology and Geochemistry UB RAS, Yekaterinburg). The slags formed as a result of bloomery iron production. Their formation temperature is estimated in a range of 1177 °С on the basis of eutectic crystallization of wustite and fayalite. The Shuvakish plant was supplied with marsh iron ore, which was most likely extracted in the nearest Moleben swamp located to the north from the plant.
Keywords: Central Urals, Shuvakish plant, bloomery production, mineralogy, iron, fayalite.
Received 26.01.2021, accepted 25.02.20201
Yu.V. Erokhin, Institute of Geology and Geochemistry UB RAS, ul. Akademika Vonsovskogo 15, Yekaterinburg, 620016 Russia;
erokhin-yu@yandex.ru
A.V. Zakharov, Institute of Geology and Geochemistry UB RAS, ul. Akademika Vonsovskogo 15, Yekaterinburg, 620016 Russia;
L.V. Leonova, Institute of Geology and Geochemistry UB RAS, ul. Akademika Vonsovskogo 15, Yekaterinburg, 620016 Russia;
- Alekseev V.V. (2001) [Metallurgical factories of the Urals XVII–XX centuries. Encyclopedia]. Yekaterinburg, Academkniga, 536 p. (in Russian)
- Artemyev D.A., Ankushev M.N., Blinov I.A., Kotlyarov V.A., Lukpanova Ya.A. (2018) Mineralogy and origin of slags from the 6th kurgan of the Taksay 1 burial complex, Western Kazakhstan. Canadian Mineralogist, 56, 883–904.
- Asochakova E.M., Konovalenko S.I. (2010) [Geochemistry of oolitic and swamp iron ores of the Tomsk region]. Vestnik Tomskogo gosudarstvennogo universiteta [Bulletin of Tomsk State University], (341), 222–225. (in Russian)
- Bowen N.L., Schairer J.F. (1932) The system FeO– SiO2. American Journal Science, 24, 117–213.
- Britvin S.N., Krivovichev S.V., Armbruster T.(2016) Ferromerrillite, Ca9NaFe2+(PO4)7, a new mineral from the Martian meteorites, and some insights merrillite-tuite transformation in shergottites. European Journal of Mineralogy, 28, 125–136.
- Buchwald V.F. (2005) Iron and steel in ancient times. The Royal Danish Academy of Sciences and Letters. Copenhagen, 372 p.
- Bulakh A.G. (1999) [General mineralogy. Second edition]. St. Petersburg, SPbGU, 356 p. (in Russian)
- Bykov V.M. (1924) [Sverdlovsk is the capital of the Urals. Guidebook for 1925 years]. Sverdlovsk, Uralkniga, 230 p. (in Russian)
- Chesnokov B.V., Shcherbakova Е.P. (1991) [Mineralogy of burnt dumps of the Chelyabinsk coal basin (experience of mineralogy of technogenesis)]. Мoscow, Nauka, 152 p. (in Russian)
- Chupin N.K. (1873) [Geographical and statistical dictionary of the Perm province]. Perm, 415 p. (in Russian)
- Erokhin Yu.V. (2012) [Mineralogy of slags of the Rezh nickel plant]. Mineralogiya tekhnogeneza [Mineralogy of technogenesis], (13). Miass, IMin UrO RAN, 50–64. (in Russian)
- Erokhin Yu.V., Kozlov P.S. (2010) [Fayalite from slags of the Central Urals copper melting plant (Revda)]. Mineralogiya tekhnogeneza [Mineralogy of technogenesis], (11). Miass, IMin UrO RAN, 32–40. (in Russian)
- Kozlov P.S., Erokhin Yu.V., Kozlova I.V. (2011) [Fayalite slags of the Mariinsky processing plant]. Mineralogiya tekhnogeneza [Mineralogy of technogenesis], (12). Miass, IMin UrO RAN, 39–50. (in Russian)
- Kramar S., Lux J., Pristacz H., Mirtic B., Rogan-Smuc N. (2015) Mineralogical and geochemical characterization of Roman slag from the archaeological site near Mosnje (Slovenia). Materials and technology, 49(3), 343–348.
- Kuleshevich L.V., Larkina N.Yu., Minina I.S. (2010) [Iron minerals in the collection of the Museum of Precambrian Geology: limonite and hematite ores of Karelia]. Geologiya i poleznyye iskopayemyye Karelii. Sbornik nauchnykh trudov [Geology and mineral deposits of Karelia. Collection of scientifc papers]. Petrozavodsk, KarNTs RAN, (13), 131–138. (in Russian)
- Kurlaev E.A. (1993) [Metallurgical plants of the Middle Urals of the 17th–early 18th centuries (preliminary results of study of monuments of industrial archeology)]. Pamyatniki drevney kul’tury Urala i Zapadnoy Sibiri. Sbornik nauchnykh trudov [Monuments of ancient culture of the Urals and Western Siberia. Collection of scientifc papers]. Yekaterinburg, Nauka, 223–234. (in Russian)
- Kurlaev E.A. (1994) [Study of the Shuvakish plant and problems of industrial archeology]. Polzunovskiye chteniya. Tezisy konferentsii [Polzunov readings. Conference abstracts]. Yekaterinburg, Bank kulturnoy informatsii, 33– 36. (in Russian)
- Kurlaev E.A. (2002) [Archeological study of the Shuvakish iron plant of the beginning of the 18th century]. Ural’skiy istoricheskiy vestnik [Urals Historical Bulletin], (8), 164–183. (in Russian)
- Kurlaev E.A., Kostoglou P.L., Koroneos K.P. (1995) [Study of relics of the Shuvakish and Tumashevsky plants in 1994 year]. Yezhegodnik Nauchno-issledovatel’skogo instituta russkoy kul’tury-1994 [Yearbook of the Research Institute of Russian Culture-1994], Yekaterinburg, UrGU, 129–131. (in Russian)
- Okrugin A.V., Vasilyeva A.E., Dyachkovsky A.V. (2014) [Mineral and chemical composition of the old homemade Yakut iron]. Nauka i tekhnika v Yakutii [Science and technology in Yakutia], (26), 22–26. (in Russian)
- Pleiner R. (2000) Iron in archaeology: The European bloomery smelters. Archeologicky ustav AVCR, 400 p.
- Portillo-Blanco H., Zuluaga M.C., Ortega L.A., Alonso-Olazabal A., Cepeda-Ocampo J.J., Salcedo A.M. (2020) Mineralogical characterization of slags from the Oiola Site (Biscay, Spain) to assess the development in bloomery iron smelting technology from the Roman Period to the Middle Ages. Minerals, 10, 321.
- Preobrazhensky А.А. (1972) [Urals and Western Siberia in the late 16th–early 18th centuries]. Мoscow, Nauka, 372 p. (in Russian)
- Selskiene A. (2007) Examination of smelting and smithing slags formed in bloomery iron-making process. Chemija, 18(2), 22–28.
- Stepanov I., Borodianskiy K., Eliyahu-Behar A. (2020) Assessing the quality of iron ores for bloomery smelting: laboratory experiments. Minerals, 10, 33.
- Strobele F., Wenzel T., Kronz A., Hildebrandt L.H., Markl G. (2010) Mineralogical and geochemical characterization of high-medieval lead-silver smelting slags from Wiesloch near Heidelberg (Germany) – an approach to process reconstruction. Archeology Anthropology Sciences, 2, 191–215.
- Warchulski R., Gaweda A., Janeczek J., Kadziolka-Gawel M. (2016) Mineralogy and origin of coarse-grained segregations in the pyrometallurgical Zn-Pb slags from Katowice-Welnowiec (Poland). Mineralogy and Petrology, 110, 681–692.
MINERALOGY № 1 2021