Mineralogy of the Vorontsovskoe gold deposit (Northern Urals)
A.V. Kasatkin, S.Yu. Stepanov, M.V. Tsyganko, R. Škoda, F. Nestola, J. Plášil, E. Makovicky, A.A. Agakhanov, R.S. Palamarchuk
УДК 553.411.071:549 | https://doi.org/10.35597/2313-545X-2022-8-1-1 | Читать PDF (RUS) |
The Vorontsovskoe gold deposit (Northern Urals) is unique in both Russia and the world because of the diverse and original Tl–Hg–Mn–As–Sb–S mineralization. Based on the available literature and our data, we present a list of 210 minerals found at this deposit. Eight of them are new minerals discovered by the authors: vorontsovite, ferrovorontsovite, tsygankoite, gladkovskyite, luborzakite, pokhodyashinite, gungerite, and auerbakhite. In addition, 41 minerals are found for the frst time in the Russian Federation and 89 minerals are new for the deposit. We defned nine major ore mineral assemblages, including seven ones related to carbonate breccias. They contain more than 70 rare sulfdes, tellurides and sulfosalts, including 31, 12, and 9 minerals with Tl, Hg and Mn, respectively, as species-defning elements. The paper also describes these mineral assemblages and minerals of the Vorontsovskoe deposit.
Keywords: Vorontsovskoe deposit, Northern Urals, ore mineral assemblage, carbonate breccia, Tl-Hg-Mn sulfosalt, new mineral, frst fnd in Russia. Received 18.10.2021, accepted 15.01.2022A.V. Kasatkin, Fersman Mineralogical Museum of RAS, Leninsky pr. 18/2 Moscow, 119071 Russia; anatoly.kasatkin@gmail.com
S.Yu. Stepanov, Institute of Geology and Geochemistry UB RAS, ul. Akademika Vonsovskogo 15, Yekaterinburg, 620016 Russia;M.V.
Tsyganko, Mineralogical Museum «Shtufnoi Kabinet», ul. Vatutina 17a, Severouralsk, Sverdlovsk oblast, 624480 Russia;R.
Skoda, Masaryk University, Kotlarska 2, Brno, 61137 Czech Republic;
F. Nestola, University of Padova, Via Gradenigo 6, Padova, 35131 Italy;
J. Plasil, Institute of Physics ASCR, V.V.I., Na Slovance 1999/2, Prague, 18221 Czech Republic;
E. Makovicky, University of Copenhagen, Ostervoldgade 10, DK-1350, Copenhagen, Denmark;
A.A. Agakhanov, Fersman Mineralogical Museum of RAS, Leninsky pr. 18/2 Moscow, 119071 Russia;
R.S. Palamarchuk, South Urals Federal Research Center of Mineralogy and Geoecology UB RAS, Institute of Mineralogy, Miass, Chelyabinsk oblast, 456317 Russia
- Anastassakis E., Perry C.H. (1976) Light scattering and IR measurements in XS2 pyrite–type compounds. The Journal of Chemical Physics, 64, 3604–3609.
- Balić-Žunić T., Šćavnićar S., Engel P. (1982) The crystal structure of rebulite, Tl5As8Sb5S22. Zeitschrift für Kristallographie, 160, 109–125.
- Baryshev A.N., Zlotnik-Khotkevich A.G., Cheremisin A.A. (1993) [Vorontsovskoe gold deposit in the Northern Urals, structure and forecast-prospecting criteria]. Materiali nauchno-tekhnicheskoy konferencii NTD-92-TSNIGRI.
[Proceedings of the scientifc and technical conference 12– 24 March 1993]. Moscow, TsNIGRI, 31–32. (in Russian) - Begetnev S.V. (1998) [Morphology of «rice-like» jasperoid quartz of the Vorontsovskoe gold deposit (Northern Urals)]. Ural’skaya letnyaya mineralogicheskaya shkola–98 [Urals Summer Mineralogical School-98]. Yekaterinburg, UGGU, 67–68. (in Russian)
- Berlepsch P., Makovicky E., Balić-Žunić T. (2001) Crystal chemistry of sartorite homologues and related sulfosalts. Neues Jahrbuch für Mineralogie-Abhandlungen, 176, 45–66.
- Bezsmertnaya M.S., Kozerenko S.V., Kolpako-va N.N. (1973) [Seligmannite and sinnerite from Elbrus polymetallic deposit]. In.: Issledovania v oblasti rudnoy mineralogii [Researches in Area of Ore Mineralogy]. Moscow, Nauka, 5–14. (in Russian)
- Biagioni C., Bonaccorsi E., Moëlo Y., Orlandi P., Bindi L., D’Orazio M., Vezzoni S. (2014) Mercury–arsenic sulfos-alts from Apuan Alps (Tuscany, Italy). III. Arsiccioite, AgHg2T-lAs2S6, a new mineral from the Monte Arsiccio mine: occur¬rence, crystal structure, and crystal chemistry of the routhierite isotypic series. Mineralogical Magazine, 78, 101–117.
- Biagioni C., George L.L., Cook N.J., Makovicky E., Moëlo Y., Pasero M., Sejkora J., Stanley C.J., Welch M.D., Bosi F. (2020) The tetrahedrite group: nomenclature and classifcation. American Mineralogist, 105, 109–122.
- Biagioni C., Moëlo Y. (2017) Lead–antimony sulfosalts from Tuscany (Italy). XVIII. New data on the crystal–chemistry of boscardinite. Mineralogical Magazine, 81, 47–60.
- Biagioni C., Moëlo Y., Favreau G., Bourgoin V., Boulliard J.-C. (2015) Crystal structure of Pb-rich chabournéite from Jas Roux, France. Acta Crystallographica, 71, 81–88.
- Bindi L. Biagioni C., Keutsch F.N. (2018) Oyonite, Ag3Mn2Pb4Sb7As4S24, a new member of the lillianite homologous series from the Uchucchacua base-metal deposit, Oyon district, Peru. Minerals, 8, 192.
- Bindi L., Nestola F., Guastoni A., Secco L. (2010) The crystal structure of dalnegroite, Tl5–xPb2x(As,Sb)21–xS34: a masterpiece of structural complexity. Mineralogical Magazine, 74, 999–1012.
- Bindi L., Nestola F., Makovicky E., Guastoni A., de Battisti L. (2014) Tl-bearing sulfosalt from the Lengenbach quarry, Binn valley, Switzerland: Philrothite, TlAs3S5. Mineralogical Magazine, 78, 1–9.
- Bindi L., Popova V., Bonazzi P. (2003) Uzonite, As4S5, from the type locality: single-crystal X-ray study and efects of exposure to light. The Canadian Mineralogist, 41, 1463–1468.
- Bindi L., Stanley C.J., Spry P.G. (2015) New structu-ral data reveal benleonardite to be a member of the pearceite–polybasite group. Mineralogical Magazine, 79, 1213–1221.
- Bobrov V.N. (2013) [Vorontsov’s treasure. Prospecting and discoveries]. Karpinsk, Perspektiva, 32 p. (in Russian)
- Boev B., Jovanovski G., Makreski P. (2012) Geology and mineralogy of Allchar Sb–As–Tl–Au deposit. Geologica Macedonica, 3, 215–233.
- Bonazzi P., Bindi L., Keutsch F.N. (2012) Mangano-quadratite, AgMnAsS3, a new manganese-bearing sulfosalt from the Uchucchacua polymetallic deposit, Lima department, Peru: description and crystal structure. American Mi¬neralogist, 97, 1199–1205.
- Bonazzi P., Menchetti S., Pratesi G. (1995) The crystal structure of pararealgar, As4S4. American Mineralogist, 80, 400–403.
- Bryzgalov I.A., Krivitskaya N.N., Spiridonov E.M. (2011) [First fnd of minerals of jordanite-geocronite-schulzite series at one deposit (Darasun, Eastern Transbaikalia)]. Doklady RAN [Doklady Russian Academy of Sciences], 438(5), 635–638. (in Russian).
- Burri G., Graeser S., Marumo F., Nowacki W. (1965) Imhoft, ein neues Thallium–arsensulfosalz aus dem Lengenbach (Binnatal, Kanton Wallis). Chimia, 19, 499–500. (in German)
- Cheremisin A.A., Zlotnik-Khotkevich A.G. (1997) [The Vorontsovskoe gold deposit]. Rudy i metally [Ores and Metals], (1), 59–70. (in Russian)
- Chvileva T.N., Bezsmertnaya M.S., Spiridonov E.M., Agroskin A.S., Papayan G.V., Vinogradova R.A., Lebedeva S.I., Zavyalov E.N., Filimonova A.A., Petrov V.K., Rautian L.P., Sveschnikova O.L. (1988) [Handbook of ore minerals in refected light]. Moscow, Nedra, 504 p. (in Russian).
- Dickson F.W., Radtke A.S., Peterson J.A. (1979) Ellisite, Tl3AsS3 a new mineral from the Carlin gold deposit, Nevada, and associated sulfde and sulfosalt minerals. American Mineralogist, 64, 701–707.
- Dincă G., Popescu G.C. (2019) Manganoquadratite and Cd-manganoquadratite from Săcărâmb Au–Ag–Te ore deposit, Metaliferi Mountains, Romania. Carpathian Journal of Earth and Environmental Sciences, 14(1), 131–136.
- Engel P. (1980) Die Kristallstruktur von synthetischem Parapierrotit, TlSb5S8. Zeitschrift für Kristallographie, 151, 203–216. (in German)
- Fleet M.E. (1973) The crystal structure and bonding of lorandite, Tl2As2S4. Zeitschrift für Kristallographie, 138, 147–160.
- Forneris R. (1969) Infrared and Raman spectra of realgar and orpiment. American Mineralogist, 54(7–8), 1062–1074.
- Frost R.L., Bahfenne S., Keefe E.C. (2010) Raman spectroscopic study of the mineral gerstleyite Na2(Sb,As)8S13 ∙ 2H2O and comparison with some heavy-metal sulfdes. Journal of Raman Spectroscopy, 41(12), 1779–1783.
- Gladkovsky B.A. (2002) [The history of discovery of the Vorontsovskoe gold deposit]. Ural’skiy geologicheskiy zurnal [Urals Geological Journal], (5), 165–170. (in Rus-sian)
- Gostojić M., Edenharter A., Nowacki W., Engel P. (1982) The crystal structure of synthetic Tl2MnAs2S5. Zeitschrift fur Kristallographie, 158, 43–51.
- Graeser S., Berlepsch P., Makovicky E., Balić-Zu nić T. (2001) Sicherite, TlAg (As,Sb) S , a new sulfosalt mineral from Lengenbach (Binntal, Switzerland): descrip-tion and structure determination. American Mineralogist, 86, 1087–1093.
- Graeser S., Schwander H., Wulf R. (1995) Stalderite TlCu(Zn,Fe,Hg)2As2S6 – a new mineral related to routhierite: description and crystal structure determination. Sch-weizerische mineralogische und petrographische Mitteilungen, 75, 337–345.
- Grigoriev N.A., Sazonov V.N., Murzin V.V. (1991) [Mineral balance of gold in Carlin type rocks]. Mineral’niy balans khimicheskikh elementov v gornykh porodakh i rudakh Urala [Mineral balance of chemical elements in rocks and ores of the Urals], 2, 14–19. (in Russian)
- Gruzdev V.S., Stepanov V.I., Shumkova N.G., Chernitsova M.M., Yudin R.N., Bryzgalov I.A. (1972) [Galkhaite, HgAsS2, a new mineral from arsenic–antimony– mercury deposits of the USSR]. Doklady AN SSSR [Doklady Academy of Sciences USSR], 205(5), 1194–1197. (in Russian)
- Gvozdev V.I., Grebennikova A.A., Vakh A.S., Goryachev N.A., Fedoseev, D.G. (2020) [Mineral evolution of during formation of gold–rare–metals ores of Sredne-Golgotai deposit (Eastern Transbaikalia)]. Russian Journal of Pacifc Geology, 14, 66–86.
- Isakovich I.Z. (1996) [Mineralogical aureoles of the Vorontsovskoe gold deposit]. Otechestvennaja geologiya [Native Geology], 8, 26–30. (in Russian)
- Ivashchenko V.I., Valkama M., Sundblad K., Golubev A.I., Alekseev V.Y. (2011) [New data on mineralogy and metallogeny of scarns of Pitkyaranta ore region]. Doklady Akademii nauk [Doklady Earth Sciences], 440(1), 1307–1311.
- Johan Z., Mantienne J., Picot P. (1981) La chabournéite, un nouveau minéral thallifère. Bulletin de Minéralogie, 104, 10–15 (in French).
- Kabanov A.A. (2001) [Oxidized ores as a new geological and economic type of supergene gold deposits: example of the Vorontsovskoe deposit in the Urals]. [Dissertation of Candidate of Geological-Mineralogical Sciences]. St. Pe¬tersburg, 142 p. (in Russian)
- Kasatkin A.V. (2019) New fndings of rare minerals from former Soviet Union countries. Mineralogical Almanac, 24(2), 4–47.
- Kasatkin A.V., Nestola F., Agakhanov A.A., Škoda R., Karpenko V.Y., Tsyganko M.V., Plášil J. (2018a) Vorontsovite, (Hg5Cu)Σ6TlAs4S12, and ferrovorontsovite, (Fe5Cu) Σ6TlAs4S12: The Tl- and Tl–Fe-analogues of galkhaite from the Vorontsovskoe gold deposit, Northern Urals, Russia. Minerals, 8, 185.
- Kasatkin A.V., Makovicky E., Plášil J., Škoda R., Agakhanov A.A., Karpenko V.Y., Nestola F. (2018b) Tsygankoite, Mn8Tl8Hg2(Sb21Pb2Tl)Σ24S48, a new sulfosalt from the Vorontsovskoe gold deposit, Northern Urals, Russia. Minerals, 8, 218.
- Kasatkin A.V., Makovicky E., Plášil J., Škoda R., Chukanov N.V., Stepanov S.Y, Agakhanov A.A., Nestola F. (2019) Gladkovskyite, MnTlAs3S6, a new thallium sulfosalt from the Vorontsovskoe gold deposit, Northern Urals, Russia. Journal of Geosciences, 64(3), 207–218.
- Kasatkin A.V., Makovicky E., Plášil J., Škoda R., Agakhanov A.A., Stepanov S.Y., Palamarchuk R.S.(2020a) Luboržákite, Mn2AsSbS5, a new member of pavonite homologous series from Vorontsovskoe gold deposit, Northern Urals, Russia. Mineralogical Magazine, 84, 738–745. Kasatkin A.V., Pautov L.A. (2020) [Optical proper¬ties of vorontsovite and ferrovorontsovite: new data]. Novye dannye o mineralakh [New Data on Minerals], 54(2), 69– 72. (in Russian)
- Kasatkin A.V., Plášil J., Makovicky E., Chukanov N.V., Škoda R., Agakhanov A.A., Tsyganko M.V.(2020c) Gungerite, IMA 2020-009. CNMNC Newsletter No. 56. Mineralogical Magazine, 84, 485–488.
- Kasatkin A.V., Nestola F., Škoda R., Chukanov N.V., Agakhanov A.A., Belakovskiy D.I. (2020d) Hingganite-(Nd), Nd2□Be2Si2O8(OH)2, a new gadolinite-supergroup mineral from Zagi Mountain, Pakistan. The Canadian Mineralogist, 58, 549–562.
- Kasatkin A.V., Plášil J., Makovicky E., Chukanov N.V., Škoda R., Agakhanov A.A., Stepanov S.Y., Palamarchuk R.S. (2021) Auerbakhite, MnTl2As2S5, a new thal¬lium sulfosalt from the Vorontsovskoe gold deposit, Northern Urals, Russia. Journal of Geosciences, 66(2), 89–96.
- Kasatkin A.V., Plášil J., Makovicky E., Hornfeck W., Chukanov N.V., Škoda R., Agakhanov A.A., Tsyganko M.V. (2022a) Gungerite, TlAs5Sb4S13, a new thallium sulfosalt with a giant structure containing covalent As–As bonds. American Mineralogist, in press, DOI: doi.org/10.2138/am-2022-8003.
- Kasatkin A.V., Plášil J., Makovicky E., Škoda R., Agakhanov A.A., Tsyganko M.V. (2022b) Pokhodyashinite, CuTlSb2(Sb1-xTlx)AsS7-x, a new thallium sulfosalt from the Vorontsovskoe gold deposit, Northern Urals, Russia. Journal of Geosciences, 67(1), in press, DOI: 10.3190/jgeo-sci.342.
- Kemkina R.A., Kemkin I.V., Khanchuk A.I., Ivanov V.V. (2018) [First fnd of trace metal minerals at the Al-baza gold deposit]. Doklady Akamenii nauk [Doklady Earth Sciences], 481, 943–947.
- Kharbish S. (2011) Raman spectroscopic investigations of some Tl-sulfosalt minerals containing pyramidal (As,Sb)S3 groups. American Mineralogist, 96(4), 609–616.
- Kharbish S., Libowitzky E., Beran A. (2009) Raman spectra of isolated and interconnected pyramidal XS3 groups (X = Sb, Bi) in stibnite, bismuthinite, kermesite, stephanite and bournonite. European Journal of Mineralogy, 21(2), 325–333.
- Korzhinsky D.S. (1948) [Petrology of the Turinsky skarn copper deposits]. Moscow, AN SSSR, 148 p. (in Russian)
- Krasnobaev A.A., Fershtater G.B., Bogomolov E.S., Larionov A.N., Berezhnaya N.G. (2007) [Auerbakh pluton: zircons, age, polychronism]. Ezhegodnik-2006 IGiG UrO RAN [Yearbook-2006 of the Institute of Geology and Geochemistry UB RAS]. Yekaterinburg, IGG UrO RAN, 191–196. (in Russian)
- Makovicky E. (2019) Algorithms for calculations of homologue order N in the homologous series of sulfosalts. European Journal of Mineralogy, 31, 83–97.
- Makovicky E., Plášil J., Kasatkin A.V., Škoda R. (2021) The crystal structure of Tl2.355Sb5.984As4.591S17, the lead-free end-member of the chabournéite homeotypic family. The Canadian Mineralogist, 59, 533–549.
- Makovicky E., Topa D. (2014) Lillianites and andorites: new life for the oldest homologous series of sulfosalts. Mineralogical Magazine, 78, 387–414.
- Makovicky E., Topa D. (2015) Crystal chemical formula for sartorite homologues. Mineralogical Magazine, 79, 25–31.
- Makreski P., Jovanovski G., Boev B. (2014) Micro-Raman spectra of extremely rare and endemic Tl-sulfosalts from Allchar deposit. Journal of Raman Spectroscopy, 45(7), 610–617.
- Melkov V. G., Belova L. N., Gorshkov A. I., Ivanova O. A., Sivtsov A.V., Boronikhin V. A. (1983) [New data on lermontovite]. Mineralogicheskiy zhurnal [Mineralogical Journal], 55(1), 82–87. (in Russian)
- Merlet C. (1994) An accurate computer correction program for quantitative electron probe microanalysis. Micro-chimica Acta, 114/115, 363–376.
- Minceva-Sukarova B., Jovanovski G., Makreski P., Soptrajanov B., Grifth W., Willis R., Grzetic I. (2003) Vibrational spectra of MIMIIIS2 type synthetic minerals (MI = Tl or Ag and MIII = As or Sb). Journal of Molecular Structure, 651–653, 181–189.
- [Mineralogy of the Urals: arsenides and stibnides. Tellurides. Selenides. Fluorides. Chlorides and bromides]. (1991) Sverdlovsk, UO AN SSSR, 215 p. (in Russian)
- Minina O.V. (1994) [Auerbakh complex ore-magmatic system in the Central Urals]. Otechestvennaya geologiya [Native Geology], (7), 17–23. (in Russian)
- Miyawaki R., Hatert F., Pasero M., Mills S. J. (2021) IMA Commission on New Minerals, Nomenclature and Classifcation (CNMNC) – Newsletter 63. European Journal of Mineralogy, 33, 639–646.
- Moëlo Y., Makovicky E., Mozgova N.N., Jambor J.L., Cook N., Pring A., Paar W., Nickel E.H., Graeser S., Karup–Möller S., Balic-Žunic T., Mumme W.G., Vur-ro F., Topa D., Bindi L., Bente K., Shimizu M. (2008) Sulfosalt systematics: a review. Report of the sulfosalt subcommittee of the IMA Commission on Ore Mineralogy. European Journal of Mineralogy, 20, 7–46.
- Moëlo Y., Marcoux E., Makovicky E., Karup-Möller S., Legendre O. (1987) Homologues de la lillianite (gustavite, vikingite, heyrovskyite riche en Ag et Bi…) de l’indice à W-As-(Pb,Bi,Ag) de La Roche-Balue (Loire Atlantique, France). Bulletin de Minéralogie, 110, 43–64. (in French)
- Mozgova N.N., Borodaev Yu.S., Senderova V.M., Ronami G.N., Yakovlevskaya T.A. (1971) [The fnd of heteromorphite in a collection of the Mineralogical Museum of Academy of Sciences of the USSR]. Trudy mineralogi-cheskogo muzeia im. Fersmana [Proceedings of the Fersman Mineralogical Museum], 20, 114–119. (in Russian)
- Murzin V.V., Bushmakin A.F., Sustavov S.G., Shcherbachov D.K. (1996) [Clerite MnSb2S4 – a new mineral from Vorontsovskoe gold deposit in the Urals]. Zapiski VMO [Proceedings of the Russian Mineralogical Society], 125(3), 95–101. (in Russian)
- Murzin V.V., Naumov E.A., Azovskova O.B., Varlamov D.A., Rovnushkin M.Yu., Pirajno F. (2017) The Vorontsovskoe Au–Hg–As ore deposit (Northern Urals, Russia): geological setting, ore mineralogy, geochemistry, geochronology and genetic model. Ore Geology Reviews, 85, 271–298.
- Murzin V.V., Sazonov V.N. (1990) [Mineralogical features of Carlin type gold mineralization in an andesite volcano-plutonic belt (Urals)]. Mineralogiya mestorozh-deniy Urala: tezisy dokladov II regionalnogo soveshchaniya «Mineralogiya Urala» [Mineralogy of the Urals Deposits: Abstracts of the II Regional Meeting «Mineralogy of the Urals»]. Sverdlovsk, UrO AN SSSR, 95–98. (in Russian)
- Murzin V.V., Sazonov V.N., Grigoriev N.A., Ryabinin V.F. (1990) A genetic model for Carlin-type gold ores in the Urals. Proceedings of Eighth Quaddrennial IAGOD Symposium, Schweizerbart’sche Verlagsbuchhandlung, Stuttgart, 647–652.
- Murzin V.V., Sazonov V.N., Ronkin Yu.L. (2010) [Model of formation of the Carlin type Vorontsovskoe gold deposit in the Urals: new data and problems]. Litosfera [Lithosphere], 6, 66–73. (in Russian).
- Murzin V.V., Sustavov S.G. (1997) [Prospects of discovery of new ore minerals in the Urals]. Struktura i evolutsiya mineral’nogo mira. Materiali k mezhdunarodnomu mineralogicheskomu seminaru [Structure and Evolution of the Mineral World. Materials of the International Mineralogical Seminar]. Syktyvkar, 105–106. (in Russian)
- Murzin V.V., Varlamov D.A. (2010) [Gold–sulfdesulfosalt mineral assemblage in breccias with siliceous fragments from the Vorontsovskoe deposit (Central Urals)]. Vestnik Uralskogo otdeleniya RMO [Bulletin of the Urals Branch of the Russian Mineralogical Society], 7, 92–100 (in Russian).
- Murzin V.V., Varlamov D.A., Rovnushkin M.Yu. (2011) [Assemblage of native arsenic and arsenopyrite at the Vorontsovskoe gold deposit (Northern Urals)]. Vestnik Uralskogo otdeleniya RMO [Bulletin of the Urals Branch of the Russian Mineralogical Society], 8, 80–87. (in Russian)
- Nestola F., Guastoni A., Bindi L., Secco L. (2009) Dalnegroite,Tl5–xPb2x(As,Sb)21–xS34, a new thallium sulphosalt from Lengenbach quarry, Binntal, Switzerland. Mine-ralogical Magazine, 73(6), 1027–1032.
- Orlandi P., Biagioni C., Bonaccorsi E., Moëlo Y., Paar W.H. (2012) Lead antimony sulfosalts from Tuscany (Italy). XII. Boscardinite, TlPb4(Sb7As2)Σ9S18, a new species from Monte Arsiccio mine: occurrence and crystal structure. The Canadian Mineralogist, 50, 235–251.
- Orlandi P., Biagioni C., Moëlo Y., Bonaccorsi E., Paar W.H. (2013) Lead antimony sulfosalts from Tuscany (Italy). XIII. Protochabournéite, ~ Tl2Pb(Sb9–8As1–2)Σ10S17, from the Monte Arsiccio mine: occurrence, crystal structure and relationship with chabournéite. The Canadian Miner¬alogist, 51, 475–494.
- Plášil J., Kasatkin A.V., Škoda R., Stepanov S.Yu.(2018) [Parapierrotite from the Vorontsovskoe gold deposit, Northern Urals, Russia: crystal structure and chemical composition]. Zapiski RMO [Proceedings of the Russian Miner-alogical Society], 147(1), 68–78.
- Popov V.A., Kolisnichenko S.V. (2008) [On the mineralogy of carbonatites of Russian Brazil in the Southern Urals]. Ural’skij mineralogicheskij sbornik [Ural mineralogical digest], 15, 75–84. (in Russian)
- Raber T., Roth P. (2018) The Lengenbach quarry in Switzerland: Classic locality for rare thallium sulfosalts. Minerals, 8, 409.
- Radtke A. (1985) Geology of the Carlin gold deposit, Nevada. USGS Professional Paper 1267, 124 p.
- Rakhov E.V. [The ore-bearing breccias of the Vorontsovskoe deposit: composition, genesis and role in formation of gold mineralization]. Abstract of Dissertation of Candi¬date of Geological-Mineralogical Sciences. Yekaterinburg, 1999, 17 p. (in Russian)
- Rindzunskaya N.M., Berzon R.O., Polyakova T.P.(1995a) [Geological and genetic bases of forecast and prospect of gold deposits in weathering mantle]. Moscow, TsNI-GRI, 300 p. (in Russian)
- Rindzunskaya N.M., Polyakova T.P., Bobrov V.N.(1995b) [Geological and mineralogical characteristics of a supergene zone of the Vorontsovskoe gold deposit]. Rudy i metally [Ores and Metals], 4, 42–52. (in Russian)
- Roth P., Raber T., Favreau G. and Meisser N. (2017) Thallium sulfosalts from the Shimen As deposit, Hunan, China. Mineral Up, 4(6), 8–22.
- Rovnushkin M.Yu., Gulyaeva T.Ya., Galakhova O.L. (2010) [Occurrence of K-feldspar metasomatosis within the Vorontsovskoe gold deposit (Northern Urals)]. Ezhegodnik-2009 IGG UrO RAN [Yearbook-2009 of the Institute of Geology and Geochemistry UB RAS]. Yekaterinburg, IGG UrO RAN, 241–244. (in Russian)
- Ryabinin V.F., Murzin V.V., Surganov A.V. (1992) [Features of gold and silver distribution in sulfdized skarns of the Vorontsovskoe gold deposit]. Ezhegodnik-1991 IGG UrO AN SSSR [Yearbook-1991 of the Institute of Geology
and Geochemistry UB AS USSR]. Yekaterinburg, IGG UrO RAN, 65–66. (in Russian) - Savel’eva K.P., Kostromin D.A. (1991) [Polygenic and polychronous metasomatosis of one of the Ural gold deposits]. Rudonosnye metasomaticheskie formatsii Urala [Ore-Bearing Metasomatic Complexes of the Urals], Sverdlovsk, UrO AN SSSR, 77–78. (in Russian)
- Savel’eva K.P., Kostromin D.A. Melnichuk G.D. (1991) [Features of formation of gold deposits of the Northern Urals]. Materialy po geologii i metallogenii Urala [Materials on Geology and Metallogeny of the Urals. Sverdlovsk, UrO AN SSSR, 60–64. (in Russian)
- Sazonov V.N., Artemenko N.A., Voronina L.K. (1995) [Light micas of the Vorontsovskoe gold deposit (Northern Urals)]. Ezhegodnik-1994 IGG UrO RAN [Year-book-1994 of the Institute of Geology and Geochemistry UB RAS], Yekaterinburg, IGG UrO RAN, 93–94. (in Russian)
- Sazonov V.N., Murzin V.V., Grigor’ev, N.A. (1998) [Vorontsovskoe gold deposit: an example of Carlin-type mineralization in the Urals, Russia]. Geologiya rudnykh mestorozhdenii [Geology of Ore Deposits], 40(2), 139–151.
- Sazonov V.N., Murzin V.V., Grigoriev N.A. (1990a) [Gold content of ore in area of andesite marginal belts: example of the Urals]. Doklady AN SSSR [Doklady Academy of Sciences USSR], 314(3), 677–681. (in Russian)
- Sazonov V.N., Murzin V.V., Grigoriev N.A., Gladkovsky B.A. (1990b) [The Carlin-type gold mineralization in the Urals]. Novye dannye po zolotorudnym mestorozhdeni-yam Urala [New Data on the Urals Gold Deposits]. Sverdlovsk, UrO AN SSSR, 26–49 (in Russian).
- Sazonov V.N., Murzin V.V., Grigoriev N.A., Gladkovsky B.A. (1991a) [Endogenic mineralization of the Devonian andesite volcano-plutonic complex (Urals)]. Sverdlovsk, UrO AN SSSR, 184 p. (in Russian)
- Sazonov V.N., Murzin V.V., Grigoriev N.A., Ogorodnikov V.N., Ryabinin V.F. (1991b) [Unconventional gold mining in the Urals]. Materialy po geologii i metallogenii zolota Urala [Materials on Geology and Metallogeny of the Urals Gold]. Sverdlovsk, UrO AN SSSR, 3–36. (in Russian)
- Sazonov V.N., Murzin V.V., Shumilov I.A. (1993) [Isotopic-geochemical model of the Auerbakh ore feld (Northern Urals)]. Doklady Akademii nauk [Doklady of Academy of Sciences], 331(4), 456–458. (in Russian)
- Soroka E.I., Pritchin M.E., Azovskova O.B., Rovnushkin M.Yu., Lyutoev V.P., Smoleva I.V. (2018) [Physical and chemical studies of vein carbonates of the Vorontsovskoe gold deposit]. Vestnik Permskogo universiteta [Bulletin of the Perm University], 17(1), 41–51. (in Russian)
- Soroka E.I., Pritchin M.E., Azovskova O.B., Rovnushkin M.Yu., Smoleva I.V., Galakhova O.L. (2017) [Vein carbonates of ore-bearing rocks of the Vorontsovskoe gold deposit]. Problemy mineralogii, petrografi i metallogenii. Nauchnye chteniya pamyati P.N.
- Chirvinskogo [Problems of Mineralogy, Petrography and Metallogeny. Scientifc Readings in Memory of P.N. Chirvinsky], 20, 242–248. (in Russian)
- Spiridonov E.M., Petrova I.V., Dashevskaya D.M., Balashov E.P., Klimova L.M. (1990) [Roshchinite Ag19 Pb10Sb51S96 – new mineral of the andorite group]. Zapiski VMO [Proceedings of the Russian Mineralogical Society], 119(5), 32–43. (in Russian)
- Stanley C.J., Criddle A.J., Chisholm J.E. (1986) Benleonardite, a new mineral from the Bambolla mine, Moctezuma, Sonora, Mexico. Mineralogical Magazine, 50, 681–686.
- Stepanov S.Yu., Palamarchuk R.S., Cherepanov A.V., Proskurnin V.F. (2019) [Geological and genetic type of the Vorontsovskoe gold deposit (Northern Urals)]. Ural’skaya mineralogicheskaya shkola-2019 [Urals Mineralogical School-2019]. Yekaterinburg, IGG UrO RAN, 163–168. (in Russian)
- Stepanov S.Yu, Sharpenok L.N., Antonov A.V.(2017) [Fluid-explosive breccias of the Vorontsovskoe gold deposit (The North Urals)]. Zapiski RMO [Proceedings of the Russian Mineralogical Society], 146(1), 29–43. (in Rus¬sian)
- Stepanov S.Yu., Palamarchuk R.S., Varlamov D.A., Kiseleva D.V., Sharpyonok L.N., Škoda R., Kasatkin A.V. (2021) The Features of Native Gold in Ore‐bearing Breccias with Realgar‐orpiment Cement of the Vorontsovskoe Deposit (Northern Urals, Russia). Minerals, 11, 541.
- Thomas R., Davidson P. (2010) Hambergite-rich melt inclusions in morganite crystals from the Muiane pegmatite, Mozambique and some remarks on the paragenesis of hambergite. Mineralogy and Petrology, 100(3–4), 227–239.
- Tomkins A.G., Frost B.R., Pattison D.R.M. (2006) Arsenopyrite melting during metamorphism of sulfde ore deposits. The Canadian Mineralogist, 44, 1045–1062.
- Topa D., Graeser S., Stoeger B., Raber T., Stanley C. (2019) Drechslerite, IMA 2019-061. CNMNC News¬letter No. 52. Mineralogical Magazine, 83, https://doi. org/10.1180/mgm.2019.73
- Topa D., Kolitsch U. (2018) The crystal chemistry of rathite based on new electron-microprobe data and single-crystal structure refnements: the role of thallium. Minerals, 8, 466.
- Topa D., Kolitsch U., Makovicky E., Stanley C.(2017a) Écrinsite, AgTl3Pb4As11Sb9S36, a new thallium-rich homeotype of baumhauerite from the Jas Roux sulphosalt deposit, Parc national des Écrins, Hautes-Alpes, France. Eu¬ropean Journal of Mineralogy, 29, 689–700.
- Topa D., Makovicky E. (2017) The crystal structure of veenite. Mineralogical Magazine, 81, 355–368.
- Topa D., Makovicky E., Putz H., Zagler G. (2013) Lopatkaite, IMA 2012–083. CNMNC Newsletter No. 15, February 2013, page 11. Mineralogical Magazine, 77, 1–12.
- Topa D., Makovicky E., Stöger B., Stanley C.(2017b) Heptasartorite, Tl7Pb22As55S108, enneasartorite, Tl6Pb32As70S140 and hendekasartorite, Tl2Pb48As82S172, three members of the anionomission series of ‘sartorites’ from the Lengenbach quarry at Binntal, Wallis, Switzerland. Eu-ropean Journal of Mineralogy, 29, 701–712.
- Topa D., Keutsch F.N., Kolitsch U., Lengauer C., Giester G., Stanley C. (2021a) Shimenite, IMA 2019-069, in: CNMNC Newsletter 63. European Journal of Mineralogy, 33, 639–646.
- Topa D., Kolitsch U., Stoeger B., Keutsch F., Stanley C. (2021b) Dewitite, IMA 2019-098, in: CNMNC Newsletter 63. European Journal of Mineralogy, 33, 639–646.
- Vakh A. S., Avchenko O. V., Gvozdev V. I., Goryachev N. A., Karabtsov A. A., Vakh E. A. (2019) Minerals of the Pb–As–Sb–S and Cu–Pb–As–Sb–S systems in ores of the Berezitovoe gold-polymetallic deposit, Upper Amur region, Russia. Geology of Ore Deposits, 61, 256–273.
- Vakh A.S., Khomich V.G., Boriskina N.G., Santosh M. (2016) The Berezitovoe gold-polymetallic deposit (Upper Amur region, Russia): structure, mineralogy and genetic as-pects. Geoscience Frontiers, 7(3), 483–494.
- Vasiliev V.I. (2011) New data on the composition of metacinnabar and Hg-sphalerite with an isomorphous Cd admixture. Russian Geology and Geophysics, 52(7), 701–708.
- Vikent’eva O., Vikentev I. (2016) Occurrence modes of As, Sb, Te, Bi, Ag in sulfde assemblages of gold deposits of the Urals. 3rd International Conference on Competitive Materials and Technology Processes (IC–CMTP3). IOP Conference Series: Materials Science and Engineering, 123, 012028.
- Vikentyev I.V., Tyukova E.E., Murzin V.V., Viken-tyeva O.V., Pavlov L.G. (2016) [Vorontsovskoe gold deposit. Geology, gold modes, genesis]. Yekaterinburg, Fort DialogIset, 204 p. (in Russian)
- Vikentyev I.V., Tyukova E.E., Vikentyeva O.V., Chugaeva A.V., Dubinina E.O., Prokofev V.Yu., Murzin V.V. (2019) Vorontsovka Carlin-style gold deposit in the North Urals: Mineralogy, fuid inclusion and isotope data for genetic model. Chemical Geology, 508, 144–166.
- Volkov A.V., Sidorov A.V. (2016) [Geological-genetic model of Carlin type gold deposits]. Litosfera [Lithosphere], (6), 145–165. (in Russian)
- White N.C., Hedenquist J.W. (1995) Epithermal gold deposits: styles, characteristics and exploration. SEG News-letter, (23), 9–13.
- Wilson J.R., Robinson P.D., Wilson P.N., Stanger L.W., Salmon G.L. (1991) Gillulyite, Tl2(As,Sb)8S13, a new thallium arsenic sulfosalt from the Mercur gold deposit, Utah. American Mineralogist, 76, 653–656.
- Yazeva R.G., Puchkov V.N., Bochkarev V.V. (1991) [Geodynamics and metallogeny of the eastern paleoconti-nental margin and marginal volcanic-plutonic belts of the Urals]. Geodinamika i metallogeniya Urala [Geodynamics and Metallogeny of the Urals]. Yekaterinburg, IGG UrO RAS, 43–45. (in Russian)
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